Sodium Hydroxide → Tris-(lauryloxyethyl)-amine
Reaktionsgleichung
[CH2:1]([O:13][CH2:14][CH2:15][N:16]([CH2:20][CH2:21][O:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])[CH2:17][CH2:18][OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[OH-].[Na+].S([O-])(O[CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH3:52])(=O)=O>>[CH2:52]([O:19][CH2:18][CH2:17][N:16]([CH2:20][CH2:21][O:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])[CH2:15][CH2:14][O:13][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])[CH2:51][CH2:50][CH2:49][CH2:48][CH2:47][CH2:46][CH2:45][CH2:44][CH2:43][CH2:42][CH3:41]Komponenten
4
Versuchsvorschrift
20 grams (0.042 mole) of di-(lauryloxyethyl)-hydroxyethyl amine (the second fraction recovered in Example 12) were reacted with 2.0 grams (0.05 mole) of sodium hydroxide and 12.1 grams (0.042 mole) of lauryl sulfate, Na salt using the procedure of Example 12. Purification of the product again using the procedure of Example 12, gave 32 grams of a yellow oily product having an amine number of 85.6.