Sodium Hydroxide → Tris-(lauryloxyethyl)-amine

HRID 1906250

Reaktionsgleichung

[CH2:1]([O:13][CH2:14][CH2:15][N:16]([CH2:20][CH2:21][O:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])[CH2:17][CH2:18][OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[OH-].[Na+].S([O-])(O[CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH3:52])(=O)=O>>[CH2:52]([O:19][CH2:18][CH2:17][N:16]([CH2:20][CH2:21][O:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])[CH2:15][CH2:14][O:13][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])[CH2:51][CH2:50][CH2:49][CH2:48][CH2:47][CH2:46][CH2:45][CH2:44][CH2:43][CH2:42][CH3:41]

Komponenten

Edukt 3

HCID 14798Sodium Hydroxide

HCID 4329331Npc315034

HCID 17993396Di-(lauryloxyethyl)-hydroxyethyl amine

Produkt 1

HCID 20041967Tris-(lauryloxyethyl)-amineAusbeute 116,5 %

Versuchsvorschrift

20 grams (0.042 mole) of di-(lauryloxyethyl)-hydroxyethyl amine (the second fraction recovered in Example 12) were reacted with 2.0 grams (0.05 mole) of sodium hydroxide and 12.1 grams (0.042 mole) of lauryl sulfate, Na salt using the procedure of Example 12. Purification of the product again using the procedure of Example 12, gave 32 grams of a yellow oily product having an amine number of 85.6.

Aufarbeitung

customPurification of the product

Quellen und Nachweise

ORD-Eintrag: ord-e1b2328b4ee74c6a954e131200e875a2
Quelldatensatz: uspto-grants-1987_03
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04650865

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