Methyl iodide → 1,4-Dimethylpyridinium Iodide

HRID 1911862Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1911862
[N:1]1[CH:6]=[CH:5][C:4]([CH3:7])=[CH:3][CH:2]=1.[CH3:8][I:9]>C1(C)C=CC=CC=1>[I-:9].[CH3:8][N+:1]1[CH:6]=[CH:5][C:4]([CH3:7])=[CH:3][CH:2]=1

Komponenten

4

Edukt 2

HCID 6328Methyl iodideHCID 79634-Methylpyridine

Produkt 1

HCID 2006031,4-Dimethylpyridinium IodideAusbeute 67,2 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 1140TolueneLösungsmittel

Versuchsvorschrift

To a solution of 4-picoline (18.6 g, 0.2 mol) in toluene (100 mL), methyl iodide (56.8 g, 0.4 mol) was added dropwise at room temperature. After the addition, the mixture was stirred at room temperature for 5 hrs. The precipitate was collected by filtration, washed with toluene and dried under vacuum to give Compound 7 as an off-white solid (31.6 g, 67%). The structure of Compound 7 is given below:

Aufarbeitung

  1. additionAfter the addition
  2. filtrationThe precipitate was collected by filtration
  3. washwashed with toluene
  4. customdried under vacuum

Quellen und Nachweise

ORD-Eintrag
ord-5ab71f0c6b6f4c3e84c0ac06846cb5ac
Quelldatensatz
uspto-grants-2013_12
Patentnummer
US08604204B2

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