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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 1919753Erstellt: 26. Oktober 2026

4-[1,1,1,3,3,3-Hexafluoro-2-(methoxymethyl)oxypropan-2-yl]-2-propylphenyl benzyl ether → 4-(1,1,1,3,3,3-Hexafluoro-2-(methoxymethoxy)propan-2-yl)-2-propylphenol

https://huagongshe.com/reaction/1919753

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
Edukt4-[1,1,1,3,3,3-Hexafluoro-2-(methoxymethyl)oxypropan-2-yl]-2-propylphenyl benzyl etherHCID 59201148—
KatalysatorHCID 178418390HCID 178418390—
LösungsmittelMethanolHCID 887—
Produkt4-(1,1,1,3,3,3-Hexafluoro-2-(methoxymethoxy)propan-2-yl)-2-propylphenolHCID 59201037104,7%

Reaktionsschritte

A 10% palladium carbon catalyst (30 mg) was added to a mixed solution of 4-[1,1,1,3,3,3-hexafluoro-2-(methoxymethyl)oxypropan-2-yl]-2-propylphenyl benzyl ether (264.9 mg, 0.61 mmol) in methanol (10 mL), followed by hydrogenation overnight. The catalyst was separated from the reaction solution by filtration, followed by concentration under reduced pressure to obtain 221.1 mg of the title compound (yield: 100%) as a pale yellow oil.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS08168666B2
Quelldatensatzuspto-grants-2012_05
ORD IDord-fa4bdb4d15b34aa0813217f1dea8373d
Quellennotizuspto-grants-2012_05