Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Pentitol | HCID 827 | — |
| Edukt | D-Arabitol | HCID 94154 | — |
| Edukt | HCID 178418489 | HCID 178418489 | — |
| Produkt | D-Arabitol | HCID 94154 | — |
| Produkt | (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 107526 | — |
| Produkt | aldehydo-D-Xylose | HCID 644160 | — |
| Produkt | D-Xylulose | HCID 5289590 | — |
Reaktionsschritte
It is known from European Patent No. 421,882, of which the Applicant is proprietor, to obtain xylitol syrups having a xylitol content of 80% to 90%, the remainder being essentially composed of D-arabitol, pentitol of the natural D series of sugars. These syrups, which are not very viscous and which are particularly well adapted to the crystallization of xylitol, are obtained by microbiological conversion of glucose to D-arabitol, microbiological oxidation of D-arabitol, to D-xylulose, enzymatic isomerization of D-xylulose to D-xylose and then catalytic hydrogenation of the mixture of D-xylulose and D-xylose to xylitol and D-arabitol. These xylitol syrups, which do not contain L-arabitol or galactitol but only D-arabitol as accompanying polyol, permit easy extraction of three crops of pure xylitol crystals.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patentnummer | US05728225 |
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| Quelldatensatz | uspto-grants-1998_03 |
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| ORD ID | ord-51173d9d709c45cdbf8cf8891134c0bf |
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| Quellennotiz | uspto-grants-1998_03 |
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