HCID 20097836, Verbindung → HCID 59627195, Verbindung
Reaktionsgleichung
Br[CH2:2][C:3]1[CH:8]=[C:7]([Cl:9])[CH:6]=[C:5]([CH3:10])[C:4]=1[N+:11]([O-:13])=O.BrC[C:16]1C=CC=C(C(F)(F)F)[C:17]=1[N+:26]([O-])=O.ClC1C=C(C)C([N+]([O-])=[O:38])=C(C)C=1>>[NH2:26][CH:17]1[CH2:2][C:3]2[C:4](=[C:5]([CH3:10])[CH:6]=[C:7]([Cl:9])[CH:8]=2)[N:11]([OH:13])[C:16]1=[O:38]Komponenten
4
Versuchsvorschrift
1-(Bromomethyl)-5-chloro-3-methyl-2-nitrobenzene (38) Following the procedure for the preparation of 1-(bromomethyl)-2-nitro-3-(trifluoromethyl)benzene (17) in Example 3, reaction of 5-chloro-1,3-dimethyl-2-nitrobenzene (37) provided the title compound as a solid (50%). 1H NMR (400 MHz, CDCl3) δ 2.36 (m, 3H), 4.43 (s, 2H), 7.28 (m, 1H), 7.37 (m, 1H).