HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Oxygen → 1-Carboxy-3-nitro-5-adamantanol
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Oxygen | HCID 977 | — |
| Edukt | 3-Nitrotricyclo(3.3.1.13,7)decane-1-carboxylic acid | HCID 39239 | — |
| Lösungsmittel | Acetic Acid | HCID 176 | — |
| Produkt | 1-Carboxy-3-nitro-5-adamantanol | HCID 22463570 | 80% |
Reaktionsschritte
In an atmosphere of oxygen, the mixture of 10 mmole of 1-carboxy-3-nitroadamantane, 1 mmole of NHPI, 0.05 mmole of V(AA) 3 and 25 mL of acetic acid was allowed to react for 4 hours at 85° C. The reaction products were analyzed by gas-mass spectroscopy, and as a result, 1-carboxy-3-nitro-5-adamantanol was formed in a 80% yield.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06392104B1 |
| Quelldatensatz | uspto-grants-2002_05 |
| ORD ID | ord-32be10716b084944abeb66e5d07af09e |
| Quellennotiz | uspto-grants-2002_05 |