(R)-5-(2-Azido-1-hydroxyethyl)-8-(benzyloxy)quinolin-2(1H)-one → HCID 66988389, Verbindung
Reaktionsgleichung
N(C[C@@H](C1C=CC(OCC2C=CC=CC=2)=C2C=1C=CC(=O)N2)O)=[N+]=[N-].[Si]([O:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][O:40][CH2:41][CH2:42][CH2:43][CH2:44][C:45]1[CH:50]=[CH:49][C:48]([N:51]([CH3:86])[C:52]([C:54]2[CH:55]=[C:56]([S:60]([C:63]3[CH:64]=[C:65]4[C:70](=[C:71]([CH3:73])[CH:72]=3)[N:69]=[CH:68][C:67]([C:74]([NH2:76])=[O:75])=[C:66]4[NH:77][C:78]3[CH:83]=[CH:82][CH:81]=[C:80]([O:84][CH3:85])[CH:79]=3)(=[O:62])=[O:61])[CH:57]=[CH:58][CH:59]=2)=[O:53])=[CH:47][CH:46]=1)(C(C)(C)C)(C)C>>[OH:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][O:40][CH2:41][CH2:42][CH2:43][CH2:44][C:45]1[CH:50]=[CH:49][C:48]([N:51]([CH3:86])[C:52]([C:54]2[CH:55]=[C:56]([S:60]([C:63]3[CH:64]=[C:65]4[C:70](=[C:71]([CH3:73])[CH:72]=3)[N:69]=[CH:68][C:67]([C:74]([NH2:76])=[O:75])=[C:66]4[NH:77][C:78]3[CH:83]=[CH:82][CH:81]=[C:80]([O:84][CH3:85])[CH:79]=3)(=[O:61])=[O:62])[CH:57]=[CH:58][CH:59]=2)=[O:53])=[CH:47][CH:46]=1Komponenten
3
Edukt 2
Produkt 1
Versuchsvorschrift
The title compound was synthesized in a manner analogous to that described for Intermediate 5, using Intermediate 78 as a substrate. ES/MS calcd. for C42H49N4O7S+ 753.3. Found m/z=753.4 (M+H)+.