Benzyl Alcohol → Benzyl 4-carboxyphenylacetate

HRID 1950653Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1950653
C(C1C=CC(CC(O)=O)=CC=1)=[O:2].C(O)C1C=CC=CC=1.[CH:21]([C:23]1[CH:28]=[CH:27][C:26]([CH2:29][C:30]([O:32][CH2:33][C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)=[O:31])=[CH:25][CH:24]=1)=[O:22]>>[CH2:33]([O:32][C:30]([CH2:29][C:26]1[CH:25]=[CH:24][C:23]([C:21]([OH:2])=[O:22])=[CH:28][CH:27]=1)=[O:31])[C:34]1[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=1

Komponenten

4

Edukt 3

HCID 244Benzyl AlcoholHCID 113441872-(4-formylphenyl)acetic AcidHCID 19966221Benzyl 2-(4-formylphenyl)acetate

Produkt 1

HCID 19966080Benzyl 4-carboxyphenylacetateAusbeute 80,6 %

Versuchsvorschrift

Synthesized from (4-formylphenyl)acetic acid (1 g) and benzyl alcohol (730 mg) according to an analogous synthetic method to Example 806, benzyl (4-formylphenyl)acetate (1.4 g) was used according to an analogous synthetic method to Preparation Example 53 to provide the title compound (1.2 g).

Aufarbeitung

  1. customwas used according to an analogous synthetic method to Preparation Example 53

Quellen und Nachweise

ORD-Eintrag
ord-c45b78abdee74abfaacf72d90fd3e6ec
Quelldatensatz
uspto-grants-2013_03
Patentnummer
US08399520B2

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