Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | m-Chloroperbenzoic acid | HCID 70297 | — |
| Edukt | 1-Phenyl-1-butene | HCID 123088 | — |
| Edukt | Sodium Bicarbonate | HCID 516892 | — |
| Lösungsmittel | Dichloromethane | HCID 6344 | — |
| Produkt | 2-(2-Phenylethyl)oxirane | HCID 135955 | — |
Reaktionsschritte
3-chlorobenzenecarboperoxoic acid (12.1 g, 54.0 mmol) is added in one portion to a solution of 3-buten-1-ylbenzene (7.15 g, 54.1 mmol) in CH2Cl2 at 0° C. followed by warming to 25° C. overnight. Saturated NaHCO3 was added and the mixture separated and the resulting clear oil (8.0 g, quant.) was carried forward without further purification: LC-MS (ES) m/z=149 (M+H)+.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patentnummer | US08410158B2 |
|---|
| Quelldatensatz | uspto-grants-2013_04 |
|---|
| ORD ID | ord-4c18e56d8a4f487f8012f2a8b3b4b95b |
|---|
| Quellennotiz | uspto-grants-2013_04 |
|---|
