Triacetoxyperiodinane → tert-butyl benzyl(4-(5-chloro-1-(triisopropylsilyl)-1H-pyrrolo[2,3-b]pyridine-4-carbonyl)-bicyclo[2.2.2]octan-1-yl)carbamate

Reaktionsgleichung

[CH2:1]([N:8]([C:16]12[CH2:23][CH2:22][C:19]([CH:24]([C:26]3[C:31]([Cl:32])=[CH:30][N:29]=[C:28]4[N:33]([Si:36]([CH:43]([CH3:45])[CH3:44])([CH:40]([CH3:42])[CH3:41])[CH:37]([CH3:39])[CH3:38])[CH:34]=[CH:35][C:27]=34)[OH:25])([CH2:20][CH2:21]1)[CH2:18][CH2:17]2)[C:9](=[O:15])[O:10][C:11]([CH3:14])([CH3:13])[CH3:12])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.CC(OI1(OC(C)=O)(OC(C)=O)OC(=O)C2C=CC=CC1=2)=O>C(Cl)Cl>[CH2:1]([N:8]([C:16]12[CH2:23][CH2:22][C:19]([C:24]([C:26]3[C:27]4[CH:35]=[CH:34][N:33]([Si:36]([CH:43]([CH3:45])[CH3:44])([CH:37]([CH3:39])[CH3:38])[CH:40]([CH3:41])[CH3:42])[C:28]=4[N:29]=[CH:30][C:31]=3[Cl:32])=[O:25])([CH2:20][CH2:21]1)[CH2:18][CH2:17]2)[C:9](=[O:15])[O:10][C:11]([CH3:13])([CH3:14])[CH3:12])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1