5,7-Dimethyladamantane-1,3-diol → 1,3-Dimethyl-5-hydroxy-7-acryloyloxyadamantane
Reaktionsgleichung
[C:1](OCC12CC3CC(CC(O)(C3)C1)C2)(=[O:4])[CH:2]=[CH2:3].[CH3:18][C:19]12[CH2:29][C:23]3([OH:30])[CH2:24][C:25]([OH:28])([CH2:27][C:21]([CH3:31])([CH2:22]3)[CH2:20]1)[CH2:26]2>>[CH3:31][C:21]12[CH2:27][C:25]3([OH:28])[CH2:24][C:23]([O:30][C:1](=[O:4])[CH:2]=[CH2:3])([CH2:29][C:19]([CH3:18])([CH2:26]3)[CH2:20]1)[CH2:22]2Komponenten
3
Versuchsvorschrift
The reaction was conducted in the same manner as the step of Example 36 (2) except that 1,3-dimethyl-5,7-dihydroxyadamantane was used instead of the 1,3-dicarboxy-5-adamantanol, and, as a result, a 1,3-dimethyl-5-hydroxy-7-acryloyloxyadamantane (yield: 87%, white solid) was obtained.
Quellen und Nachweise
- ORD-Eintrag
- ord-6c67c3a798b54d3a8126d39f48f5fced
- Quelldatensatz
- uspto-grants-2001_05
- DOI