5,7-Dimethyladamantane-1,3-diol → 1,3-Dimethyl-5-hydroxy-7-acryloyloxyadamantane

HRID 1978126

Reaktionsgleichung

Reaktionsgleichung von HRID 1978126
[C:1](OCC12CC3CC(CC(O)(C3)C1)C2)(=[O:4])[CH:2]=[CH2:3].[CH3:18][C:19]12[CH2:29][C:23]3([OH:30])[CH2:24][C:25]([OH:28])([CH2:27][C:21]([CH3:31])([CH2:22]3)[CH2:20]1)[CH2:26]2>>[CH3:31][C:21]12[CH2:27][C:25]3([OH:28])[CH2:24][C:23]([O:30][C:1](=[O:4])[CH:2]=[CH2:3])([CH2:29][C:19]([CH3:18])([CH2:26]3)[CH2:20]1)[CH2:22]2

Komponenten

3

Edukt 2

HCID 5806055,7-Dimethyladamantane-1,3-diolHCID 219967831-Hydroxy-3-(acryloyloxymethyl)adamantane

Produkt 1

HCID 222287881,3-Dimethyl-5-hydroxy-7-acryloyloxyadamantaneAusbeute 87 %

Versuchsvorschrift

The reaction was conducted in the same manner as the step of Example 36 (2) except that 1,3-dimethyl-5,7-dihydroxyadamantane was used instead of the 1,3-dicarboxy-5-adamantanol, and, as a result, a 1,3-dimethyl-5-hydroxy-7-acryloyloxyadamantane (yield: 87%, white solid) was obtained.

Quellen und Nachweise

ORD-Eintrag
ord-6c67c3a798b54d3a8126d39f48f5fced
Quelldatensatz
uspto-grants-2001_05
Patentnummer
US06235851B1

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