methyl 1H-pyrrole-3-carboxylate → Methyl 5-(3-methylphenylthio)pyrrole-3-carboxylate
Reaktionsgleichung
[NH:1]1[CH:5]=[CH:4][C:3]([C:6]([O:8][CH3:9])=[O:7])=[CH:2]1.[C:10]1([CH3:18])[CH:15]=[CH:14][CH:13]=[C:12]([S:16]Cl)[CH:11]=1>>[CH3:18][C:10]1[CH:11]=[C:12]([S:16][C:5]2[NH:1][CH:2]=[C:3]([C:6]([O:8][CH3:9])=[O:7])[CH:4]=2)[CH:13]=[CH:14][CH:15]=1Komponenten
3
Versuchsvorschrift
By the method of this Example and Examples 3 and 8, methyl pyrrole-3-carboxylate is reacted with m-toluenesulfenyl chloride to yield methyl 5-(3-methylphenylthio)-pyrrole-3-carboxylate.
Quellen und Nachweise
- ORD-Eintrag
- ord-32a23a5a31004124bd2ee2eacb00316b
- Quelldatensatz
- uspto-grants-1985_04
- Patentnummer
- US04511575
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