2,4-Dichlorobenzyl alcohol → 4-[(2,4-Dichlorophenyl)methoxy]-3-nitropyridine

Reaktionsgleichung

Cl[C:2]1[CH:7]=[CH:6][N:5]=[CH:4][C:3]=1[N+:8]([O-:10])=[O:9].[Cl:11][C:12]1[CH:19]=[C:18]([Cl:20])[CH:17]=[CH:16][C:13]=1[CH2:14][OH:15]>>[Cl:11][C:12]1[CH:19]=[C:18]([Cl:20])[CH:17]=[CH:16][C:13]=1[CH2:14][O:15][C:2]1[CH:7]=[CH:6][N:5]=[CH:4][C:3]=1[N+:8]([O-:10])=[O:9]

Komponenten

Edukt 2

HCID 156842,4-Dichlorobenzyl alcohol

HCID 27357814-Chloro-3-nitropyridine

Produkt 1

HCID 686993324-[(2,4-Dichlorophenyl)methoxy]-3-nitropyridineAusbeute 89,3 %

Versuchsvorschrift

In accordance with the same procedures as in Preparation 2, except for using 4-chloro-3-nitropyridine prepared in Step 1 of Preparation 1 and 2,4-dichlorobenzyl alcohol, the titled compound was obtained as a white solid. (Yield: 89.3%)

Aufarbeitung

customIn accordance with the same procedures as in Preparation 2

Quellen und Nachweise

ORD-Eintrag: ord-ede79df66aae481aafd9e6c01bfe6736
Quelldatensatz: uspto-grants-2010_01
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US07642269B2

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