Hydrochloric Acid → Tris(dimethylaminomethyl)phosphine trihydrochloride
Reaktionsgleichung
[CH3:1][N:2]([CH2:4][P:5]([CH2:10][N:11]([CH3:13])[CH3:12])[CH2:6][N:7]([CH3:9])[CH3:8])[CH3:3].[ClH:14]>C(O)C>[ClH:14].[ClH:14].[ClH:14].[CH3:3][N:2]([CH2:4][P:5]([CH2:10][N:11]([CH3:13])[CH3:12])[CH2:6][N:7]([CH3:9])[CH3:8])[CH3:1]Komponenten
4
Edukt 2
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
A rubber-capped serum bottle containing 25 ml of ethanol was purged of air with argon, and then charged by means of a syringe with 2.31 g (11.25 mmol) of tris(dimethylaminomethyl)phosphine and 7.00 ml (42.0 mmol) of 6N hydrochloric acid. The solution, which fumed but remained clear, was shaken for 30 min and then stripped under vacuum, leaving 3.55 g (100% yield) of tris(dimethylaminomethyl)phosphine trihydrochloride as a white, crystalline solid.