Nalpha-(3-(acetylthio)-2-methoxycarbonylmethylpropanoyl]-L-lysine → Nalpha-[2-(carbamoylmethyl)-3-mercaptopropanoyl]-L-lysine
Reaktionsgleichung
C([S:4][CH2:5][CH:6]([CH2:19][C:20]([O:22]C)=O)[C:7]([NH:9][C@H:10]([C:16]([OH:18])=[O:17])[CH2:11][CH2:12][CH2:13][CH2:14][NH2:15])=[O:8])(=O)C.C(SCC(CC(OC)=O)C([NH:32][C@H](C(O)=O)CCCNC(=N)N)=O)(=O)C>>[C:20]([CH2:19][CH:6]([CH2:5][SH:4])[C:7]([NH:9][C@H:10]([C:16]([OH:18])=[O:17])[CH2:11][CH2:12][CH2:13][CH2:14][NH2:15])=[O:8])(=[O:22])[NH2:32]Komponenten
3
Versuchsvorschrift
By substituting Nα -[3-(acetylthio)-2-methoxycarbonylmethylpropanoyl]-L-lysine for the Nα -[3-acetylthio-2-methoxycarbonylmethylpropanoyl]-L-arginine in the procedure of Example 19, Nα -[2-(carbamoylmethyl)-3-mercaptopropanoyl]-L-lysine is obtained.
Quellen und Nachweise
- ORD-Eintrag
- ord-a54dc37925ad4c65bfe755631c55b72a
- Quelldatensatz
- uspto-grants-1980_04