Aniline → 1-phenyl-1H-1,2,4-triazol-3-amine

HRID 2063651Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2063651
C1([C:7]2O[N:10]=[C:9]([NH2:12])[N:8]=2)C=CC=CC=1.[NH2:13][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>>[C:14]1([N:13]2[CH:7]=[N:8][C:9]([NH2:12])=[N:10]2)[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

Komponenten

3

Edukt 2

HCID 6115AnilineHCID 23054465-Phenyl-1,2,4-oxadiazol-3-amine

Produkt 1

HCID 218217441-phenyl-1H-1,2,4-triazol-3-amineAusbeute 87 %

Versuchsvorschrift

This compound was prepared from 5-phenyl-[1,2,4]oxadiazol-3-ylamine (Journal of Organic Chemistry 28, 1812 (1963) and aniline, via the rearrangement described by Ruccia et al., Journal of Heterocyclic Chemistry 8, 137 (1971). The title compound was isolated as a slightly brownish solid in a yield of 87%. MS ISP (m/e): 161.2 (100) [(M+H)+].

Quellen und Nachweise

ORD-Eintrag
ord-b489db41bb9b418ba091df64ab8fc0b1
Quelldatensatz
uspto-grants-2012_10
Patentnummer
US08288403B2

Notizen zur Reaktion

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