Ethylene Oxide → 9,9-Bis(hydroxyphenyl)fluorene

HRID 2067705

Reaktionsgleichung

Reaktionsgleichung von HRID 2067705
OCCO[C:5]1[CH:10]=[CH:9][C:8]([C:11]2([C:24]3[CH:29]=[CH:28][C:27](OCCO)=[CH:26][CH:25]=3)C3C=CC=CC=3C3C2=CC=CC=3)=[CH:7][CH:6]=1.[CH2:34]1[O:36][CH2:35]1.[OH:37][C:38]1[CH:43]=[CH:42][C:41]([C:44]2([C:57]3C=C[C:60]([OH:63])=[CH:59][CH:58]=3)[C:56]3[CH:55]=[CH:54][CH:53]=[CH:52][C:51]=3[C:50]3[C:45]2=[CH:46][CH:47]=[CH:48][CH:49]=3)=[CH:40][CH:39]=1.OCCCOC1C=CC(C2(C3C=CC(OCCCO)=CC=3)C3C=CC=CC=3C3C2=CC=CC=3)=CC=1.ClCCCO>>[OH:63][C:60]1[CH:59]=[CH:58][CH:57]=[CH:44][C:45]=1[C:50]1([C:49]2[CH:48]=[CH:47][CH:46]=[CH:35][C:34]=2[OH:36])[C:28]2[CH:29]=[CH:24][CH:25]=[CH:26][C:27]=2[C:56]2[C:51]1=[CH:52][CH:53]=[CH:54][CH:55]=2.[C:38]1(=[O:37])[C:39]2[C:40]([C:7]3[C:8]([CH:11]=2)=[CH:9][CH:10]=[CH:5][CH:6]=3)=[CH:41][CH:42]=[CH:43]1

Komponenten

7

Edukt 5

HCID 6354Ethylene OxideHCID 123133-Chloro-1-propanolHCID 767169,9-Bis(4-hydroxyphenyl)fluorene2×HCID 37644049,9-Bis[4-(2-hydroxyethoxy)phenyl]fluoreneHCID 212578909,9-Bis[4-(3-hydroxypropoxy)phenyl]fluorene

Produkt 2

HCID 144384769,9-Bis(hydroxyphenyl)fluoreneHCID 22281833Fluoreneone

Versuchsvorschrift

Compounds for introducing the unit (A3) can be obtained by reacting 9,9-bis(hydroxyphenyl)fluorenes with compounds (alkylene oxide, haloalkanol, etc.) corresponding to the groups R3 and R4. For example, 9,9-bis[4-(2-hydroxyethoxy)phenyl]fluorene can be obtained by adding ethylene oxide to 9,9-bis(4-hydroxyphenyl)fluorene, and 9,9-bis[4-(3-hydroxypropoxy)phenyl]fluorene can be obtained, for example, by reacting 9,9-bis[4-hydroxyphenyl]fluorene with 3-chloropropanol under an alkaline condition. In addition, 9,9-bis(hydroxyphenyl)fluorene can be obtained by a reaction between a fluorenone (9-fluorenone, etc.) and a corresponding phenol, and 9,9-bis(4-hydroxyphenyl)fluorene can be obtained, for example, by a reaction between a phenol and 9-fluorenone.

Aufarbeitung

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Quellen und Nachweise

ORD-Eintrag
ord-bd4988b3b4714218b61c1879eeec42df
Quelldatensatz
uspto-grants-2012_10
Patentnummer
US08293861B2

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