3-Ethyl-4-hydroxy-5-methylbenzonitrile → HCID 178436628, Verbindung

HRID 2069411Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2069411
[CH3:1][C:2]1([CH3:21])[O:6][CH:5]([CH2:7][O:8][C:9]2[C:18]([CH3:19])=[CH:17][C:12]([C:13]([NH:15][OH:16])=[NH:14])=[CH:11][C:10]=2[CH3:20])[CH2:4][O:3]1.[CH2:22](C1C=C(C=C(C)C=1O)C#N)C>>[CH3:1][C:2]1([CH3:21])[O:6][C@H:5]([CH2:7][O:8][C:9]2[C:10]([CH3:20])=[CH:11][C:12]([C:13]([NH:15][OH:16])=[NH:14])=[CH:17][C:18]=2[CH2:19][CH3:22])[CH2:4][O:3]1

Komponenten

3

Edukt 2

HCID 597599503-Ethyl-4-hydroxy-5-methylbenzonitrileHCID 178426655HCID 178426655, Verbindung

Produkt 1

HCID 178436628HCID 178436628, Verbindung

Versuchsvorschrift

The title compound is obtained as a beige oil (0.86 g) in analogy to rac-4-(2,2-dimethyl-[1,3]dioxolan-4-ylmethoxy)-N-hydroxy-3,5-dimethyl-benzamidine starting from 3-ethyl-4-hydroxy-5-methyl-benzonitrile and L-alpha-beta-isopropyliden glycerol; LC-MS: tR=0.67 min, [M+H]+=308.99.

Quellen und Nachweise

ORD-Eintrag
ord-11e05694afda49269417016ab37fae7d
Quelldatensatz
uspto-grants-2012_10
Patentnummer
US08299086B2

Notizen zur Reaktion

Wird geladen…