HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
m-Chloroperbenzoic acid → Pyridine, 2-[[(2-methylphenyl)methyl]sulfinyl]-, 1-oxide
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | m-Chloroperbenzoic acid | HCID 70297 | — |
| Edukt | 2-(2-methylphenylmethylthio)pyridine N-oxide | HCID 45692352 | — |
| Lösungsmittel | Chloroform | HCID 6212 | — |
| Produkt | Pyridine, 2-[[(2-methylphenyl)methyl]sulfinyl]-, 1-oxide | HCID 501068 | — |
Reaktionsschritte
To a vigorously stirred solution of 6.9 gm (0.03 mol) of 2-(2-methylphenylmethylthio)pyridine N-oxide in 50 ml of chloroform maintained at 0° to 10° C. is slowly added a solution of 6 gm (0.03 mol) MCPBA (85%) in 100 ml of chloroform. When addition is complete the temperature is allowed to rise to ambient. After sixteen hours the reaction solution is washed up in the manner described in Example 139.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04050921 |
| Quelldatensatz | uspto-grants-1977_09 |
| ORD ID | ord-e8ec416a33d04210a65bab9cac42d512 |
| Quellennotiz | uspto-grants-1977_09 |