m-Chloroperbenzoic acid → Pyridine, 2-[[(2-methylphenyl)methyl]sulfinyl]-, 1-oxide

HRID 2072255

Reaktionsgleichung

Reaktionsgleichung von HRID 2072255
[CH3:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH2:8][S:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][N+:11]=1[O-:16].C1C=C(Cl)C=C(C(OO)=[O:25])C=1>C(Cl)(Cl)Cl>[CH3:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[CH2:8][S:9]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][N+:11]=1[O-:16])=[O:25]

Komponenten

4

Edukt 2

HCID 70297m-Chloroperbenzoic acidHCID 456923522-(2-methylphenylmethylthio)pyridine N-oxide

Produkt 1

HCID 501068Pyridine, 2-[[(2-methylphenyl)methyl]sulfinyl]-, 1-oxide

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6212ChloroformLösungsmittel2×

Versuchsvorschrift

To a vigorously stirred solution of 6.9 gm (0.03 mol) of 2-(2-methylphenylmethylthio)pyridine N-oxide in 50 ml of chloroform maintained at 0° to 10° C. is slowly added a solution of 6 gm (0.03 mol) MCPBA (85%) in 100 ml of chloroform. When addition is complete the temperature is allowed to rise to ambient. After sixteen hours the reaction solution is washed up in the manner described in Example 139.

Aufarbeitung

  1. additionWhen addition
  2. washAfter sixteen hours the reaction solution is washed up in the manner

Quellen und Nachweise

ORD-Eintrag
ord-e8ec416a33d04210a65bab9cac42d512
Quelldatensatz
uspto-grants-1977_09
Patentnummer
US04050921

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