1-[(3-Methylbutoxy)methyl]-3-nitrobenzene → 3-[(3-Methylbutoxy)methyl]aniline

HRID 2073681Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2073681
[CH3:1][CH:2]([CH3:16])[CH2:3][CH2:4][O:5][CH2:6][C:7]1[CH:12]=[CH:11][CH:10]=[C:9]([N+:13]([O-])=O)[CH:8]=1>ClCCl>[CH3:1][CH:2]([CH3:16])[CH2:3][CH2:4][O:5][CH2:6][C:7]1[CH:8]=[C:9]([CH:10]=[CH:11][CH:12]=1)[NH2:13]

Komponenten

3

Edukt 1

HCID 143301471-[(3-Methylbutoxy)methyl]-3-nitrobenzene

Produkt 1

HCID 146234833-[(3-Methylbutoxy)methyl]anilineAusbeute 97,1 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6344DichloromethaneLösungsmittel

Versuchsvorschrift

After condensing the filtrate together with the ethanol washings, the condensate was dissolved into 300 ml of dichloromethane and after washing the thus formed solution with an aqueous 10% sodium carbonate solution, then with an aqueous saturated sodium chloride solution, the thus washed solution was dried over anhydrous potassium carbonate. By distilling the solvent off from the thus dried solution and fractionally distilling the residue, 109.2 g of a fraction boiling at 105° to 106° C. (0.19 mmHg) were collected to obtain 3-[(3-methylbutoxy)methyl]aniline in a yield of 97.1%.

Aufarbeitung

  1. washafter washing the thus formed solution with an aqueous 10% sodium carbonate solution
  2. dry with materialwith an aqueous saturated sodium chloride solution, the thus washed solution was dried over anhydrous potassium carbonate
  3. distillationBy distilling the solvent off from the thus dried solution
  4. distillationfractionally distilling the residue, 109.2 g of a fraction boiling at 105° to 106° C. (0.19 mmHg)
  5. customwere collected

Quellen und Nachweise

ORD-Eintrag
ord-9fc733f94c024e5bb2976bcf7767e8ad
Quelldatensatz
uspto-grants-1990_04
Patentnummer
US04919707

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