Dimethylformamide dimethyl acetal → Hexahydro-1H,4H,7H-3a,6a,9a-triazaphenalene

HRID 2083195

Reaktionsgleichung

Reaktionsgleichung von HRID 2083195
[NH:1]1[CH2:12][CH2:11][CH2:10][NH:9][CH2:8][CH2:7][CH2:6][NH:5][CH2:4][CH2:3][CH2:2]1.[CH3:13]OC(OC)N(C)C>>[N:1]12[CH:13]3[N:9]([CH2:8][CH2:7][CH2:6][N:5]3[CH2:4][CH2:3][CH2:2]1)[CH2:10][CH2:11][CH2:12]2

Komponenten

3

Edukt 2

HCID 78373Dimethylformamide dimethyl acetalHCID 4707781,5,9-Triazacyclododecane

Produkt 1

HCID 12641659Hexahydro-1H,4H,7H-3a,6a,9a-triazaphenaleneAusbeute 73,1 %

Versuchsvorschrift

In a manner similar to that of Example 1 (C), 5.00 g (29.2 mmol) of 1,5,9-triazacyclododecane and 3.48 g of dimethylformamide dimethyl acetal were reacted to give 3.87 g of 1,5,9-triazatricyclo[7.3.1.05,13 ]tridecane as a clear, colorless liquid, bp 93° (three fractions) (0.35 mm), which solidified on standing at room temperature. One fraction was analyzed.

Quellen und Nachweise

ORD-Eintrag
ord-869639c1b39146d5aeb40b9fb9704b74
Quelldatensatz
uspto-grants-1978_04
Patentnummer
US04085106

Verknüpfte Notizen

Wird geladen…