HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Trifluoroacetic acid → 1-Bromo-2-heptyl-benzene
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Trifluoroacetic acid | HCID 6422 | — |
| Edukt | Triethylsilane | HCID 12052 | — |
| Edukt | 1-(2-Bromo-phenyl)-heptan-1-ol | HCID 22731273 | — |
| Lösungsmittel | Dichloromethane | HCID 6344 | — |
| Produkt | 1-Bromo-2-heptyl-benzene | HCID 22731318 | — |
Reaktionsschritte
Following General Procedure J and using 1-(2-Bromo-phenyl)-heptan-1-ol (1.86 g, 6.9 mmol), anhydrous dichloromethane (5 mL), trifluoroacetic acid (2.5 mL, 32.5 mmol) and triethyl silane (5 mL, 31 mmol) followed by flash column chromatography, the title compound was obtained (0.4 g, 23%).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06720423B2 |
| Quelldatensatz | uspto-grants-2004_04 |
| ORD ID | ord-2704e5e660b648e283de9f673fb2f4a1 |
| Quellennotiz | uspto-grants-2004_04 |