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N-(3-Chloropropyl)-N,N-dimethyl-1-dodecanaminium bromide → N-(N,N-dimethyl-N-dodecylammonio) propyldiallylmethylammonium Chloride Bromide

HRID 2086512
Notizen
Druckvorschau

Reaktionsgleichung

Reaktionsgleichung von HRID 2086512
[CH2:1]([CH:4]([NH2:8])[CH2:5][CH:6]=[CH2:7])[CH:2]=[CH2:3].[Br-:9].[Cl:10][CH2:11][CH2:12][CH2:13][N+:14]([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])([CH3:16])[CH3:15]>CO>[Br-:9].[Cl-:10].[CH3:15][N+:14]([CH2:13][CH2:12][CH2:11][NH2+:8][CH:4]([CH2:5][CH:6]=[CH2:7])[CH2:1][CH:2]=[CH2:3])([CH3:16])[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28]
KomponentenReaktionsbedingungenVersuchsvorschriftAufarbeitungQuellen und NachweiseNotizen zur Reaktion

Komponenten

4

Edukt 2

HCID 10861601N-(3-Chloropropyl)-N,N-dimethyl-1-dodecanaminium bromideHCID 12791689Hepta-1,6-dien-4-amine

Produkt 1

HCID 86593801N-(N,N-dimethyl-N-dodecylammonio) propyldiallylmethylammonium Chloride BromideAusbeute 73,4 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Reaktionsbedingungen

Temperatur
65 °C

Versuchsvorschrift

A mixture of 22 g of diallylmethylamine and 74 g 3-chloropropyldodecyldimethylammonium bromide was dissolved in 100 mL of methanol and the reaction mixture was stirred at 65° C. for 48 hours. After cooling to room temperature, the solvent was removed under reduced pressure. The residual viscous oil was precipitated into 800 mL of ether with rapid stirring. The ether layer was decanted and the residue was again treated with 500 mL of ether. After stirring for 15 minutes the solvent was removed and the oily residue was dried under vacuum at 35° C. for 48 hours, yielding 70 g of the product.

Aufarbeitung

  1. temperatureAfter cooling to room temperature
  2. customthe solvent was removed under reduced pressure
  3. customThe residual viscous oil was precipitated into 800 mL of ether with rapid stirring
  4. customThe ether layer was decanted
  5. additionthe residue was again treated with 500 mL of ether
  6. stirringAfter stirring for 15 minutes the solvent
  7. customwas removed
  8. customthe oily residue was dried under vacuum at 35° C. for 48 hours

Quellen und Nachweise

ORD-Eintrag
ord-8e4d5a09f0d44201bbf6d5c50f8d738b
Quelldatensatz
uspto-grants-2004_04
DOI
10.6084/m9.figshare.5104873.v1
Patentnummer
US06726905B1

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