Methyl acetoacetate → 1-Isopropyl-5-methyl-1H-pyrazole-4-carbaldehyde

HRID 2109232

Reaktionsgleichung

C(OC)(=O)CC(C)=O.Cl.C(NN)(C)C.[CH:15]1([C:18]2[N:22]([CH:23]([CH3:25])[CH3:24])[N:21]=[CH:20][C:19]=2[CH:26]=[O:27])CC1>>[CH:23]([N:22]1[C:18]([CH3:15])=[C:19]([CH:26]=[O:27])[CH:20]=[N:21]1)([CH3:25])[CH3:24]

Komponenten

Edukt 3

HCID 7757Methyl acetoacetate

HCID 855731-Isopropylhydrazine hydrochloride

HCID 196201355-cyclopropyl-1-(propan-2-yl)-1H-pyrazole-4-carbaldehyde

Produkt 1

HCID 196200991-Isopropyl-5-methyl-1H-pyrazole-4-carbaldehyde

Versuchsvorschrift

1-Isopropyl-5-methyl-1H-pyrazole-4-carbaldehyde was prepared with methyl acetoacetate and isopropyl hydrazine hydrochloride in the same manner as 5-cyclopropyl-1-isopropyl-1H-pyrazole-4-carbaldehyde (Example 49).

Quellen und Nachweise

ORD-Eintrag: ord-f9d0a8aabefe4c76839dad96ceedf0ed
Quelldatensatz: uspto-grants-2009_04
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US07514458B2

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