2-Trans,6-trans,10-trans-geranylgeranyl diphosphate(3-) → syn-Copalyl diphosphate

HRID 2113253Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2113253
[O:1]([CH2:10]/[CH:11]=[C:12](/[CH2:14][CH2:15]/[CH:16]=[C:17](\[CH3:29])/[CH2:18][CH2:19]/[CH:20]=[C:21](/[CH2:23][CH2:24][CH:25]=[C:26]([CH3:28])[CH3:27])\[CH3:22])\[CH3:13])[P:2]([O:5][P:6]([O-:9])([O-:8])=[O:7])(=[O:4])[O-:3].C/C(/CC[C@H]1[C@@]2(C)CCCC(C)(C)[C@H]2CCC1=C)=C\CO>>[CH3:13]/[C:12](/[CH2:14][CH2:15][C@H:16]1[C@@:21]2([CH3:22])[CH2:23][CH2:24][CH2:25][C:26]([CH3:28])([CH3:27])[C@@H:20]2[CH2:19][CH2:18][C:17]1=[CH2:29])=[CH:11]\[CH2:10][O:1][P:2]([O:5][P:6]([OH:9])([OH:8])=[O:7])([OH:3])=[O:4]

Komponenten

3

Edukt 2

HCID 54971052-Trans,6-trans,10-trans-geranylgeranyl diphosphate(3-)HCID 91697686Copalol

Produkt 1

HCID 5281991syn-Copalyl diphosphate

Versuchsvorschrift

Chemicals. The preparation of (E,E,E)-geranylgeranyl diphosphate (GGPP), and ent- and syn-copalyl diphosphate (CPP), from the corresponding copalol stereoisomers (Yee and Coates 1992), has been previously described (Mohan et al. 1996). Unless otherwise noted, all other chemicals were purchased from Fisher Scientific (Fairlawn, N.J., USA).

Quellen und Nachweise

ORD-Eintrag
ord-fc9042de1aa84f42b61ce73e68ff26cf
Quelldatensatz
uspto-grants-2009_04
Patentnummer
US07525016B1

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