Reaktionsgleichung
[O:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]#N.[C:8](#N)[C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1>>[C:9]1([C:8]#[C:6][C:2]2[O:1][CH:5]=[CH:4][CH:3]=2)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1Komponenten
3
Versuchsvorschrift
The procedure was identical to Example 1, with the exception that 2-furonitrile (0.175 ml; 0.186 g; 2.00 mmol) was used as a substrate instead of benzonitrile. GC analysis of the organic phase of the hydrolyzed reaction sample after 18 h at 65° C. showed the presence of 1.26 mmol (74% yield) of 2-(phenylethynyl)furan and no remaining 2-furonitrile in the reaction mixture.
Quellen und Nachweise
- ORD-Eintrag
- ord-a4b01b0c6e964a4cacdaf67e42468670
- Quelldatensatz
- uspto-grants-2006_09
- Patentnummer
- US07105707B2
Verknüpfte Notizen
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