2-Aminomethyl-4,4,8-trimethyl-nonanoic acid → 3-Amino-2-[1-(4-methyl-pentyl)-cyclopropylmethyl]-propionic Acid
Reaktionsgleichung
[NH2:1][CH2:2][CH:3]([CH2:7][C:8]([CH3:16])([CH3:15])[CH2:9][CH2:10][CH2:11][CH:12]([CH3:14])[CH3:13])[C:4]([OH:6])=[O:5].NCC(CCCCCC(C)C)C(O)=O.C1(C(OC2C(C(C)(C)C)=CC(C)=CC=2C(C)(C)C)=O)CC1>>[NH2:1][CH2:2][CH:3]([CH2:7][C:8]1([CH2:9][CH2:10][CH2:11][CH:12]([CH3:13])[CH3:14])[CH2:15][CH2:16]1)[C:4]([OH:6])=[O:5]Komponenten
4
Versuchsvorschrift
A procedure similar to that of 2-Aminomethyl-4,4,8-trimethyl-nonanoic acid was utilized to prepare 2-Aminomethyl-8-methyl-nonanoic acid from 2,6-di-t-butyl-4-methylphenyl cyclopropylcarboxylate. m/z 228.2 (M+).