HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Nitrogen oxide (N2O4) → 3-(4'-Bromophenyl)-2-nitronaphtho-[1,2-b]furan
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Nitrogen oxide (N2O4) | HCID 25352 | — |
| Edukt | 3-(4'-Bromophenyl)naphtho-[1,2-b]furan | HCID 15571603 | — |
| Lösungsmittel | Dichloromethane | HCID 6344 | — |
| Produkt | 3-(4'-Bromophenyl)-2-nitronaphtho-[1,2-b]furan | HCID 15571604 | — |
Reaktionsschritte
A solution of 2 g. of the product of step B in 50 ml. of dichloromethane is treated with 2.0 g. of dinitrogen tetraoxide, and the mixture is stirred at about 20° C. for about 18 hours. The mixture is evaporated, and the residue obtained is recrystallized from aqueous ethanol to provide yellow crystals of 3-(4'-bromophenyl)-2-nitronaphtho-[1,2-b]furan, m.p. 230°-233° C.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04231965 |
| Quelldatensatz | uspto-grants-1980_11 |
| ORD ID | ord-8f0246653e0d4b4abe351e69b7395e98 |
| Quellennotiz | uspto-grants-1980_11 |