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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 2249965Erstellt: 25. Oktober 2026

Benzyl mercaptan → (R)-3-Benzylsulfanyl-2-hydroxy-propionic acid methyl ester

https://huagongshe.com/reaction/2249965

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktBenzyl mercaptanHCID 7509—
EduktMethyl (2S)-2-oxiranecarboxylateHCID 10942355—
Produkt(R)-3-Benzylsulfanyl-2-hydroxy-propionic acid methyl esterHCID 5963932292%

Reaktionsschritte

This reaction was performed as previously described by Deechongkit, S.; You, S.-L.; Kelly, J. W. Org. Lett. 2004, 6, 497, using (S)-Methylglycidate 110a and Benzyl mercaptan. (R)-3-Benzylsulfanyl-2-hydroxy-propionic acid methyl ester 110b (7.41 g, 31.41 mmol, 92%) was isolated as a viscous oil: MS calcd. for C11H14O3S (M+H+) 227.1. found 227.3.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS07314872B2
Quelldatensatzuspto-grants-2008_01
ORD IDord-6488fa0568054c73b3ba49af5256f658
Quellennotizuspto-grants-2008_01