Carbon Tetrachloride → 4-(3-Chloropropyl)-2,6-dimethylmorpholine

HRID 2255370Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2255370
O[CH2:2][CH2:3][CH2:4][N:5]1[CH2:10][CH:9]([CH3:11])[O:8][CH:7]([CH3:12])[CH2:6]1.C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.C(Cl)(Cl)(Cl)[Cl:33]>>[Cl:33][CH2:2][CH2:3][CH2:4][N:5]1[CH2:10][CH:9]([CH3:11])[O:8][CH:7]([CH3:12])[CH2:6]1

Komponenten

4

Edukt 3

HCID 5943Carbon TetrachlorideHCID 11776TriphenylphosphineHCID 224782944-(3-Hydroxypropyl)-2,6-dimethylmorpholine

Produkt 1

HCID 197380174-(3-Chloropropyl)-2,6-dimethylmorpholine

Versuchsvorschrift

This intermediate (2.3 g.) was prepared using the procedure described in Example 4c except using 5.0 g. (28 mmoles) of 4-(3-hydroxypropyl)-2,6-dimethylmorpholine and 9.5 g. (30 mmoles) of triphenylphosphine in 50 ml. of carbon tetrachloride and was isolated as a colorless liquid.

Aufarbeitung

  1. customThis intermediate (2.3 g.) was prepared

Quellen und Nachweise

ORD-Eintrag
ord-4bca85dbe3a2417f979c381cad910a58
Quelldatensatz
uspto-grants-1993_08
Patentnummer
US05240925

Notizen zur Reaktion

Wird geladen…