1-Ethynyl-4-(4-propylcyclohexyl)benzene → HCID 86751152, Verbindung
Reaktionsgleichung
[CH2:1]([CH:4]1[CH2:9][CH2:8][C:7]([C:10]2[CH:15]=[CH:14][C:13]([C:16]#[CH:17])=[CH:12][CH:11]=2)=[CH:6][CH2:5]1)[CH2:2][CH3:3].C([CH:21]1[CH2:26][CH2:25][CH:24]([C:27]2C=[CH:31][C:30](C#C)=[CH:29][CH:28]=2)[CH2:23][CH2:22]1)CC>>[CH2:1]([CH:4]1[CH2:9][CH2:8][C:7]([C:10]2([C:11]#[C:12][C:21]3[CH:22]=[CH:23][C:24](/[CH:27]=[CH:28]/[CH2:29][CH2:30][CH3:31])=[CH:25][CH:26]=3)[CH:17]=[CH:16][CH:13]=[CH:14][CH2:15]2)=[CH:6][CH2:5]1)[CH2:2][CH3:3]Komponenten
3
Versuchsvorschrift
In the same manner as in Example 17 except that 4-(4-propylcyclohexenyl)phenylacetylene, (3.4 g, 0.015 moll was used in place of 4-(4-propylcyclohexyl)phenylacetylene, the reaction was carried out to obtain 1-(4-propylcyclohexenyl)phenyl-2-[4-(1-trans-pentenyl)phenyl]acetylene (2.7 g). Yield: 72%.
Quellen und Nachweise
- ORD-Eintrag
- ord-8fcc186de02f4dc794f926d9391ff331
- Quelldatensatz
- uspto-grants-1997_08