2,4,6-Trimethylaniline → 2-Methyl-6,11-dihydro-dibenzo[b,e]oxepine-11-carboxylic acid (2,4,6-trimethyl-phenyl)-amide

HRID 2260581Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2260581
[CH3:1][C:2]1[CH:19]=[CH:18][C:5]2[O:6][CH2:7][C:8]3[CH:17]=[CH:16][CH:15]=[CH:14][C:9]=3[CH:10]([C:11](O)=[O:12])[C:4]=2[CH:3]=1.[CH3:20][C:21]1[CH:27]=[C:26]([CH3:28])[CH:25]=[C:24]([CH3:29])[C:22]=1[NH2:23]>>[CH3:1][C:2]1[CH:19]=[CH:18][C:5]2[O:6][CH2:7][C:8]3[CH:17]=[CH:16][CH:15]=[CH:14][C:9]=3[CH:10]([C:11]([NH:23][C:22]3[C:24]([CH3:29])=[CH:25][C:26]([CH3:28])=[CH:27][C:21]=3[CH3:20])=[O:12])[C:4]=2[CH:3]=1

Komponenten

3

Edukt 2

HCID 69132,4,6-TrimethylanilineHCID 101063426,11-Dihydro-2-methyldibenz[b,e]-oxepin-11-carboxylic acid

Produkt 1

HCID 104293092-Methyl-6,11-dihydro-dibenzo[b,e]oxepine-11-carboxylic acid (2,4,6-trimethyl-phenyl)-amideAusbeute 61,5 %

Versuchsvorschrift

The similar procedures as in Example 1 were repeated except using 1.47 g of Compound A and 0.71 g of 2,4,6-trimethylaniline in place of aniline to obtain 1.20 g of Compound 9.

Quellen und Nachweise

ORD-Eintrag
ord-40dc5bf76d994de6b096fe3b1c1ee217
Quelldatensatz
uspto-grants-1995_12
Patentnummer
US05478835

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