cis-7-Nitro-2,3,4,4a,9,9a-hexahydro-1H-indeno[2,1-b]pyridin-6-ol → HCID 178519369, Verbindung
Reaktionsgleichung
[NH:1]1[C:5]2[CH:6]=[CH:7][C:8]([C:10]([OH:12])=O)=[CH:9][C:4]=2[N:3]=[CH:2]1.[N+:13]([C:16]1[C:28]([OH:29])=[CH:27][C:26]2[C@@H:25]3[C@@H:20]([NH:21][CH2:22][CH2:23][CH2:24]3)[CH2:19][C:18]=2[CH:17]=1)([O-:15])=[O:14]>>[NH:1]1[C:5]2[CH:6]=[CH:7][C:8]([C:10]([N:21]3[CH2:22][CH2:23][CH2:24][C@@H:25]4[C:26]5[CH:27]=[C:28]([OH:29])[C:16]([N+:13]([O-:15])=[O:14])=[CH:17][C:18]=5[CH2:19][C@H:20]34)=[O:12])=[CH:9][C:4]=2[N:3]=[CH:2]1Komponenten
3
Versuchsvorschrift
The title compound is prepared from 1H-benzoimidazole-5-carboxylic acid and cis-7-nitro-2,3,4,4a,9,9a-hexahydro-1H-indeno[2,1-b]pyridin-6-ol following a procedure analogous to that described in Example 1. Yield: 32% of theory; LC (method 1): tR=2.43 min; Mass spectrum (ESI+): m/z=379 [M+H]+.
Quellen und Nachweise
- ORD-Eintrag
- ord-5349dbc22c7f4176898340f3d4609310
- Quelldatensatz
- uspto-grants-2015_09