Thionyl Chloride → Sulfinylperfluorooctaneamide

HRID 227366Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 227366
[S:1](Cl)(Cl)=[O:2].C[Si](C)(C)[N:7]([Si](C)(C)C)[C:8](=[O:31])[C:9]([F:30])([F:29])[C:10]([F:28])([F:27])[C:11]([F:26])([F:25])[C:12]([F:24])([F:23])[C:13]([F:22])([F:21])[C:14]([F:20])([F:19])[C:15]([F:18])([F:17])[F:16]>>[S:1](=[N:7][C:8](=[O:31])[C:9]([F:29])([F:30])[C:10]([F:27])([F:28])[C:11]([F:25])([F:26])[C:12]([F:23])([F:24])[C:13]([F:21])([F:22])[C:14]([F:20])([F:19])[C:15]([F:18])([F:17])[F:16])=[O:2]

Komponenten

3

Edukt 2

HCID 24386Thionyl ChlorideHCID 86615112N,N-bis(trimethylsilyl)perfluorooctaneamide

Produkt 1

HCID 23161206Sulfinylperfluorooctaneamide

Versuchsvorschrift

Next, thionyl chloride (SOCl2) 2.4 g was added gradually to N,N-bis(trimethylsilyl)perfluorooctaneamide 12 g in the dry nitrogen atmosphere, which was allowed to react for two hours while being stirred. Then this was distilled and thereby sulfinylperfluorooctaneamide was obtained.

Aufarbeitung

  1. customto react for two hours
  2. distillationThen this was distilled

Quellen und Nachweise

ORD-Eintrag
ord-780d5624590a4ce0802a7cc83eceee8a
Quelldatensatz
uspto-grants-2009_07
Patentnummer
US07560301B2

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