Triethylamine → HCID 23462554, Verbindung

HRID 2286760Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2286760
[CH2:1]=[CH:2][C:3](=[O:9])[CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8].[CH3:10][CH:11]1[C:16](=[O:17])[CH2:15][CH2:14][CH2:13][C:12]1=[O:18].C(N(CC)CC)C>C(OCC)(=O)C>[CH3:10][C:11]1([CH2:1][CH2:2][C:3](=[O:9])[CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8])[C:16](=[O:17])[CH2:15][CH2:14][CH2:13][C:12]1=[O:18]

Komponenten

5

Edukt 3

HCID 8471TriethylamineHCID 709452-Methyl-1,3-cyclohexanedioneHCID 118047521,7-Octadien-3-one

Produkt 1

HCID 23462554HCID 23462554, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8857Ethyl AcetateLösungsmittel

Versuchsvorschrift

1,7-Octadien-3-one(0.24 g), 2-methyl-1,3-cyclohexanedione(0.5 g) and triethylamine (1 ml) are added to ethyl acetate (10 ml), and the mixture is stirred at room temperature for 24 hours. The triethylamine and acetic acid are evaporated off and the residue is purified by silica gel column chromatography(methylene chloride) to recover 0.39 g of the above-indicated compound. [IR 1700-1730 cm-1, 920 cm-1 ; NMR 1.10 ppm(3H, singlet, --CH3), 4.6-6.0 ppm(3H, multiplet, vinyl)].

Aufarbeitung

  1. customThe triethylamine and acetic acid are evaporated off
  2. customthe residue is purified by silica gel column chromatography(methylene chloride)
  3. customto recover 0.39 g of the above-indicated compound

Quellen und Nachweise

ORD-Eintrag
ord-4f38ba43deb04cac9a2e07775cec7896
Quelldatensatz
uspto-grants-1981_05
Patentnummer
US04267377

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