HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
(4,5-Dimethylfuran-2-yl)-(6-methyl-pyridin-2-yl)-methanol → (4,5-Dimethylfuran-2-yl)-(6-methyl-pyridin-2-yl)methanone
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | (4,5-Dimethylfuran-2-yl)-(6-methyl-pyridin-2-yl)-methanol | HCID 23078353 | — |
| Katalysator | HCID 178418406 | HCID 178418406 | — |
| Lösungsmittel | Chloroform | HCID 6212 | — |
| Produkt | (4,5-Dimethylfuran-2-yl)-(6-methyl-pyridin-2-yl)methanone | HCID 23078390 | 58,8% |
Reaktionsschritte
(4,5-Dimethylfuran-2-yl)-(6-methyl-pyridin-2-yl)-methanol (1.4 g) was dissolved in chloroform (30 ml) to prepare a solution. Manganese dioxide (5.7 g) was added to the solution, and the mixture was stirred at room temperature overnight. Further, manganese dioxide (1.8 g) was then added thereto, and the mixture was stirred overnight. The reaction solution was filtered through Celite. The solvent was removed from the filtrate by distillation under the reduced pressure to give (4,5-dimethylfuran-2-yl)-(6-methyl-pyridin-2-yl)-methanone (815 mg, yield 58%).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US07560558B2 |
| Quelldatensatz | uspto-grants-2009_07 |
| ORD ID | ord-6ab18d8b261b491b95b95d5380da68f3 |
| Quellennotiz | uspto-grants-2009_07 |