HCID 21475499, Verbindung → HCID 21475503, Verbindung
Reaktionsgleichung
[N+:1]([C:4]1C=C(N)C=[CH:8][C:9]=1NCC=C)([O-])=O.F[C:16]1[CH:21]=[CH:20][C:19]([N:22]([CH2:28][CH:29]([OH:32])[CH2:30][OH:31])[CH2:23][CH:24]([OH:27])[CH2:25][OH:26])=[CH:18][C:17]=1[N+:33]([O-:35])=[O:34]>>[N+:33]([C:17]1[CH:18]=[C:19]([N:22]([CH2:28][CH:29]([OH:32])[CH2:30][OH:31])[CH2:23][CH:24]([OH:27])[CH2:25][OH:26])[CH:20]=[CH:21][C:16]=1[NH:1][CH2:4][CH:9]=[CH2:8])([O-:35])=[O:34]Komponenten
3
Versuchsvorschrift
Synthesis as for compound 1, but with 4-fluoro-3-nitro-N,N-bis-(2,3-dihydroxypropyl)-aminobenzene instead of 4-fluoro-3-nitroaminobenzene. Working up: the reaction mixture was concentrated and the dark oil was dissolved in ethanol. Compound (3) was then precipitated with HCl gas in the form of the hydrochloride. Yellow crystals, melting point 154°-158° C.
Aufarbeitung
- concentrationWorking up: the reaction mixture was concentrated
- dissolutionthe dark oil was dissolved in ethanol
- customCompound (3) was then precipitated with HCl gas in the form of the hydrochloride