HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Potassium Carbonate → Ethyl 4-[4-(2-nitro-4-trifluoromethylphenoxy)phenoxy]-3-methoxy-2-pentenoate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Potassium Carbonate | HCID 11430 | — |
| Edukt | 4-[2-Nitro-4-(trifluoromethyl)phenoxy]phenol | HCID 23325101 | — |
| Edukt | Ethyl 4-bromo-3-methoxypent-2-enoate | HCID 53787831 | — |
| Lösungsmittel | Acetone | HCID 180 | — |
| Produkt | Ethyl 4-[4-(2-nitro-4-trifluoromethylphenoxy)phenoxy]-3-methoxy-2-pentenoate | HCID 53972465 | — |
Reaktionsschritte
A mixture of 4-(2-nitro-4-trifluoromethylphenoxy)phenol (9.36 mm)., ethyl 4-bromo-3-methoxy-2-pentenoate (12 mm.) and K2CO3 (14 mm.) in acetone (20 ml.) is refluxed for 24 hours. After filtration, the filtrate is concentrated and the oily residue chromatographed on silica gel to yield ethyl 4-[4-(2-nitro-4-trifluoromethylphenoxy)phenoxy]-3-methoxy-2-pentenoate.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04429167 |
| Quelldatensatz | uspto-grants-1984_01 |
| ORD ID | ord-f93849dfae0149c1a32605eec6e577a6 |
| Quellennotiz | uspto-grants-1984_01 |