Methyl 5-[2-(3-chlorophenyl)ethenyl]thiophene-2-carboxylate → HCID 69996930, Verbindung
Reaktionsgleichung
[Cl:1][C:2]1[CH:3]=[C:4]([CH:8]=[CH:9][C:10]2[S:14][C:13]([C:15]([O:17]C)=O)=[CH:12][CH:11]=2)[CH:5]=[CH:6][CH:7]=1.[N:19]12[CH2:26][CH2:25][CH:22]([CH2:23][CH2:24]1)[C@@H:21]([NH:27]C(C1SC(C3N=C(C)SC=3)=CC=1)=O)[CH2:20]2>>[N:19]12[CH2:26][CH2:25][CH:22]([CH2:23][CH2:24]1)[C@@H:21]([NH:27][C:15]([C:13]1[S:14][C:10]([CH:9]=[CH:8][C:4]3[CH:5]=[CH:6][CH:7]=[C:2]([Cl:1])[CH:3]=3)=[CH:11][CH:12]=1)=[O:17])[CH2:20]2Komponenten
3
Versuchsvorschrift
This compound is prepared from methyl 5-[2-(3-chlorophenyl) vinyl]-thiophene-2-carboxylate according to the procedure used to make the compound of Example 31, making non-critical variations. Yield 19%. MS for C20H21ClN2OS (ESI) (M+H)+ m/z 373.
Quellen und Nachweise
- ORD-Eintrag
- ord-292617be2d3c4138895938ecabeafc30
- Quelldatensatz
- uspto-grants-2002_12