HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
4,4'-Dihydroxybiphenyl → 4'-(2-Methylbutoxy)(1,1'-biphenyl)-4-ol
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 4,4'-Dihydroxybiphenyl | HCID 7112 | — |
| Edukt | Potassium Carbonate | HCID 11430 | — |
| Edukt | 1-Bromo-2-methylbutane | HCID 25254 | — |
| Lösungsmittel | Ethanol | HCID 702 | — |
| Produkt | 4'-(2-Methylbutoxy)(1,1'-biphenyl)-4-ol | HCID 14093815 | 58% |
Reaktionsschritte
A solution of 0.20 mole(37.2 g) of 4,4'-dihydroxybiphenyl, 0.10 mole(15.1 g) of the above 2-methyl-1-bromobutane, and 0.60 mole(33.7 g) of potassium carbonate in 300 ml of ethanol was refluxed for 16 hours. After the reaction, the reaction solution was filtered and concentrated, then purified by column chromatography to obtain 4.9 g of 4'-(2-methylbutoxy)-4-hydroxybiphenyl. (yield: 58%)
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04844835 |
| Quelldatensatz | uspto-grants-1989_07 |
| ORD ID | ord-7579d4eec5224c2fa2bdb88004109b17 |
| Quellennotiz | uspto-grants-1989_07 |