Phenyl benzoate → Phenyl benzoate samarium

HRID 231207

Reaktionsgleichung

Reaktionsgleichung von HRID 231207
[C:1]([O:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Sm:16]>COCCOC>[C:1]([O:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)(=[O:8])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1.[Sm:16]

Komponenten

4

Edukt 2

HCID 7169Phenyl benzoateHCID 23951Samarium

Produkt 1

HCID 86743198Phenyl benzoate samarium

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 80711,2-DimethoxyethaneLösungsmittel

Versuchsvorschrift

By reacting 0.85 mmole of phenyl benzoate in 6 ml of DME with 3.38 m atoms of samarium, in the conditions of example 9, a dark-brown compound (phenyl benzoate-samarium) has been obtained and treated as usually. Benzoate was quantitatively converted.

Quellen und Nachweise

ORD-Eintrag
ord-286940d6c433467f9268cdc443fc3240
Quelldatensatz
uspto-grants-1989_07
Patentnummer
US04845201

Verknüpfte Notizen

Wird geladen…