Reaktionsgleichung
[C:1]1([CH3:9])[C:2]([NH2:8])=[CH:3][C:4]([NH2:7])=[CH:5][CH:6]=1.C1C2C3C=CC(C2C=C1)C3.[CH3:20][CH2:21][CH2:22][CH2:23][CH3:24]>>[CH:22]1([C:5]2[CH:6]=[C:1]([CH3:9])[C:2]([NH2:8])=[CH:3][C:4]=2[NH2:7])[CH2:23][CH2:24][CH:20]=[CH:21]1Komponenten
4
Reaktionsbedingungen
- Temperatur
- 205 °C
Versuchsvorschrift
A 200g (1.64 mol) portion of 2,4-toluenediamine, 162g (1.23 mol, 2,45 equiv) of dicyclopentadiene, 200g (2.78 mol) of pentane, and 20.0g of an amorphous alumina-silica catalyst comprised of 13% alumina and 87% silica were charged to a 1000cc pressure vessel equipped with a mechanical stirrer. The vessel was sealed and purged with nitrogen leaving a 32 psig nitrogen blanket. The vessel contents were heated to 205° C. with stirring and were maintained at that temperature for 22 hours. The contents were cooled to 150° C. and isolated catalyst free by hot filtration. Selective removal of residual hydrocarbons by vacuum distillation and analysis by gas chromatography (GC) provides the following product mixture.
Aufarbeitung
- additionwere charged to a 1000cc pressure vessel
- customequipped with a mechanical stirrer
- customThe vessel was sealed
- custompurged with nitrogen leaving a 32 psig nitrogen blanket
- temperaturewere maintained at that temperature for 22 hours
- temperatureThe contents were cooled to 150° C.
- customisolated catalyst
- filtrationfree by hot filtration
- customremoval of residual hydrocarbons
- distillationby vacuum distillation and analysis by gas chromatography (GC)
- customprovides the following product mixture
Quellen und Nachweise
- ORD-Eintrag
- ord-f9d2888bf0c343fc99e299bc562e2391
- Quelldatensatz
- uspto-grants-1989_07
- Patentnummer
- US04845291
Verknüpfte Notizen
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