Hydrofluoric Acid → alpha-D-Mannopyranosyl fluoride
Reaktionsgleichung
[O:1]=[CH:2][C@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])O.[FH:13]>>[C@H:11]1([F:13])[O:12][C@H:3]([CH2:2][OH:1])[C@@H:5]([OH:6])[C@H:7]([OH:8])[C@@H:9]1[OH:10]Komponenten
3
Versuchsvorschrift
In the same way as described in Example 3, 1 g of D-mannose was reacted with 10 g of hydrogen fluoride. About 1 g of α-D-mannosyl fluoride ws isolated and identified by comparison with authentic material (cf. Barnett 35 al., loc. cit. in Example 3).
Quellen und Nachweise
- ORD-Eintrag
- ord-b4509466327d42939bf9fde5c84f8220
- Quelldatensatz
- uspto-grants-1989_07
- Patentnummer
- US04847372
Notizen zur Reaktion
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