Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Water | HCID 962 | — |
| Edukt | Sodium Azide | HCID 33557 | — |
| Edukt | 2-(Chloromethyl)anthraquinone | HCID 344311 | — |
| Lösungsmittel | Dimethylformamide | HCID 6228 | — |
| Produkt | 2-Azidomethylanthraquinone | HCID 20032212 | 92,5% |
Reaktionsschritte
10 g (0.039 mole) of 2-chloromethylanthraquinone [prepared according to G. Izoret, Ann. Chim., 7, 180 (1962)] are dissolved in 50 ml of N,N-dimethylformamide (DMF), and 2.53 g (0.039 mole) of sodium azide are added, with stirring. After 1 hour, the temperature is increased to 50° C. and the mixture is stirred at this temperature for 10 hours. 250 ml of water are added and the precipitate is filtered off. 9.5 g (92.3% of theory) of 2-azidomethyl-anthraquinone are obtained;
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patentnummer | US04849533 |
|---|
| Quelldatensatz | uspto-grants-1989_07 |
|---|
| ORD ID | ord-e84a37f73a2744169396aa64935a8c32 |
|---|
| Quellennotiz | uspto-grants-1989_07 |
|---|
