Ethyl sulfide → HCID 86743413, Verbindung

Reaktionsgleichung

[CH2:1]([S:3][CH2:4][CH3:5])[CH3:2].[CH2:6]([I:28])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27]>>[I-:28].[CH2:1]([S+:3]([CH2:4][CH3:5])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])[CH3:2]

Komponenten

Edukt 2

HCID 9609Ethyl sulfide

HCID 132572191-Iododocosane

Produkt 1

HCID 86743413HCID 86743413, Verbindung

Versuchsvorschrift

Diethyl sulphide is quaternized by docosyl iodide in order to obtain diethyldocosylsulphonium iodide. This iodide is then placed in an alcoholic solution with an equivalent of the TCNQ lithium salt. This gives crystals, which are recrystallized in alcohol. These crystals are constituted by the simple tetracyanoquinodimethane diethyl docosyl sulphonium salt of formula: ##STR4##

Quellen und Nachweise

ORD-Eintrag: ord-c8b229f5aef446ccb6a3461411dca00c
Quelldatensatz: uspto-grants-1989_10
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04871680

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