Potassium Carbonate → HCID 14720276, Verbindung
Reaktionsgleichung
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([NH:8][CH2:9][C:10]2[CH:11]=[N:12][CH:13]=[CH:14][CH:15]=2)=[CH:4][CH:3]=1.C(=O)([O-])[O-].[K+].[K+].[Cl:22][CH2:23][S:24](Cl)(=[O:26])=[O:25]>ClCCl>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([N:8]([CH2:9][C:10]2[CH:11]=[N:12][CH:13]=[CH:14][CH:15]=2)[S:24]([CH2:23][Cl:22])(=[O:26])=[O:25])=[CH:6][CH:7]=1Komponenten
5
Edukt 3
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
A 2.6 g. portion of 3-(4-chlorophenylaminomethyl)pyridine was dissolved in dichloromethane with stirring, and to the solution was added 2.1 g. of potassium carbonate and 2.25 g. of chloromethanesulfonyl chloride. The mixture was stirred at ambient temperature for several days, and was then worked up as described in Example 3 to obtain 0.6 g. of the desired product, m.p. 98°-100°.