Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Water | HCID 962 | — |
| Edukt | Boron tribromide | HCID 25134 | — |
| Edukt | 4-Methoxy-1-tetradecyl-benzene | HCID 20218714 | — |
| Lösungsmittel | Dichloromethane | HCID 6344 | — |
| Produkt | Tetradecylphenol | HCID 116800 | 101,7% |
Reaktionsschritte
Boron tribromide was added dropwise, under argon to an about -78° C. solution of about 12.16 g of 4-methoxy-1-tetradecyl-benzene in about 125 ml of methylene chloride. The reaction was stirred for about 21/2 hours at about -78° C., then water was added dropwise, the organic layer separated, washed with sodium bicarbonate solution and evaporated, giving about 11.8 g of the desired title compound, mp 70°-71° C.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patentnummer | US04640913 |
|---|
| Quelldatensatz | uspto-grants-1987_02 |
|---|
| ORD ID | ord-f9007c6b1efb48c18a61a71b6654494a |
|---|
| Quellennotiz | uspto-grants-1987_02 |
|---|
