Benzyl (4-hydroxyphenyl)carbamate → 4-Methoxyphenol

HRID 2359642Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2359642
[Cl:1][C:2]1[N:7]=[C:6]([O:8][C:9]2[CH:14]=[CH:13][C:12]([O:15]C)=[CH:11][CH:10]=2)[C:5]([NH2:17])=[CH:4][N:3]=1.[CH2:18]([O:25][C:26](=[O:35])[NH:27][C:28]1[CH:33]=[CH:32][C:31]([OH:34])=[CH:30][CH:29]=1)[C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1>>[CH3:6][O:8][C:9]1[CH:14]=[CH:13][C:12]([OH:15])=[CH:11][CH:10]=1.[CH2:18]([O:25][C:26](=[O:35])[NH:27][C:28]1[CH:29]=[CH:30][C:31]([O:34][C:4]2[C:5]([NH2:17])=[CH:6][N:7]=[C:2]([Cl:1])[N:3]=2)=[CH:32][CH:33]=1)[C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1

Komponenten

4

Edukt 2

HCID 293061Benzyl (4-hydroxyphenyl)carbamateHCID 58243054HCID 58243054, Verbindung

Produkt 2

HCID 90154-MethoxyphenolHCID 58247429HCID 58247429, Verbindung

Versuchsvorschrift

The title compound was prepared in a same manner to Compound 1c in Example 1. Using an adaptation of the method described in Procedures A and B, substituting (4-hydroxy-phenyl)-carbamic acid benzyl ester (prepared according to the procedure disclosed in U.S. Pat. No. 3,933,470) for 4-methoxyphenol in Procedure A, the title Compound 11a was obtained. MS: m/z 371.2 (M+H)+.

Aufarbeitung

  1. customprepared

Quellen und Nachweise

ORD-Eintrag
ord-626accc1f54b4b0db46fe846bded55f0
Quelldatensatz
uspto-grants-2014_04
Patentnummer
US08685990B2

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