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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 2377125Erstellt: 27. Oktober 2026

3-Phenoxybenzaldehyde → Cyanide

https://huagongshe.com/reaction/2377125

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
Edukt3-PhenoxybenzaldehydeHCID 38284—
Eduktgamma-CyhalothrinHCID 6440554—
Edukt(1RS)-cis-3-(Z-2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethylcyclopropanecarbonyl chlorideHCID 11334477—
ProduktCyanideHCID 5975—
Produktgamma-CyhalothrinHCID 6440554—

Reaktionsschritte

Surprisingly, the applicants have also found it is possible to make gamma-cyhalothrin in a process wherein steps b) and c) can be combined (in a one-pot process), that is a process for the preparation of gamma-cyhalothrin in which 1R cis-Z 3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cyclopropanecarboxylic acid chloride (III) is reacted with 3-phenoxy benzaldehyde (IV) and a source of cyanide to give gamma-cyhalothrin (I).

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS07468453B2
Quelldatensatzuspto-grants-2008_12
ORD IDord-0f901e5ada364bbf86243befb2b08010
Quellennotizuspto-grants-2008_12